Cassiterite

Curated by Maggie Liu · Updated:

Crystal system · Tetragonal

Cassiterite is an oxide mineral prized by collectors for its exceptional color range, with several world-class Chinese localities.

Black Octahedral Cassiterite from Xuebaoding, Pingwu, Sichuan
Tin oxide, the principal ore of tin; tetragonal.

About Cassiteriteextended article

Cassiterite is the principal ore of tin and the signature heavy mineral of the Xianghualing-Xuebaoding-Gejiu axis. Black or deep brown adamantine pyramids, often twinned into a dramatic visor or knee shape, define the species visually. China is both the largest producer of tin and the source of celebrated specimen material.

Notable varieties

  • Visor twin / knee twin (twinned crystal)
  • Wood tin (botryoidal habit)

The Chinese angle

The Xianghualing district in Hunan and Xuebaoding in Sichuan produce gem-quality cassiterite twins, often translucent reddish-brown, in matrix combinations with fluorite, beryl, and muscovite. Gejiu in Yunnan supplies the bulk industrial output.

Cassiterite — localities and judging quality

For specimens, the Xianghualing district in Hunan and Xuebaoding in Sichuan are the key Chinese sources — gemmy reddish-brown twinned crystals on muscovite or with fluorite and beryl — while the Gejiu tin district in Yunnan yields more opaque black material. Sharp “visor” or “knee” twins, adamantine lustre, translucency, and undamaged terminations drive value; the gemmy Xuebaoding twins are the most prized.

About Cassiterite

Cassiterite is an oxide mineral in the rutile group and has the chemical formula SnO2. It crystallizes in the tetragonal system and is one of the most visually varied minerals in the collector market. Its combination of structural character and global distribution make it a recognized species in both systematic and aesthetic collections.

Identification & care

Cassiterite typically forms dipyramidal ('elbow twins'), prismatic, acicular; massive, granular, rounded alluvial pebbles ('stream tin'). Its color range is broad, including black, brown, yellow, red, white, and colorless. The luster is adamantine, greasy, sub-metallic, the streak is brownish white, white, greyish, and specimens are typically transparent, translucent, opaque. The cleavage is imperfect/fair on {100}; indistinct on {110}. The fracture is irregular/uneven, sub-conchoidal, which aids identification.

Collector context

How it forms

Cassiterite forms in granite pegmatites and greisens; hydrothermal tin veins; alluvial 'stream tin' placer deposits from erosion of primary sources. It is commonly found in association with wolframite, tourmaline, columbite-tantalite, topaz, mica, quartz, arsenopyrite.

Classic Chinese localities

Dachang ore field, Yaogangxian W-Sn ore field, and Huanggang Fe-Sn deposit are each a benchmark source for cassiterite. Xianghualing Sn-polymetallic ore field and Xianghuapu Mine are an important Chinese source for the species.

Why collectors care

Cassiterite is a frequently-sought species in serious collections because its habit is recognizable, its color often strong, and its best examples unmistakable even at a distance. Chinese material has driven much of the recent visual shift in the species — sharper crystals, deeper colors, cleaner matrix.

What affects value

Value in Cassiterite is assessed, in typical order of weight, against: (1) locality provenance; (2) size relative to the species norm; (3) crystal form and termination sharpness; (4) color saturation and zoning; (5) transparency and internal clarity; (6) matrix quality and aesthetic balance; (7) condition (absence of damage, chips, or repair). Cleaning quality and verified locality documentation act as multipliers across the above.

Naming history

Cassiterite comes from the Greek kassiteros, "tin" — a word already ancient when Herodotus used it, and connected to the semi-legendary Cassiterides, the "Tin Islands" somewhere off the Atlantic coast of Europe from which Mediterranean traders obtained the metal. Tin made Bronze Age civilisation possible, and cassiterite has always been essentially its only ore.

Frequently asked questions

What is Cassiterite?

Cassiterite has the chemical formula SnO2, crystallises in the Tetragonal system, has a Mohs hardness of 6–7. Cassiterite is an oxide mineral prized by collectors for its exceptional color range, with several world-class Chinese localities.

What is the chemical formula of Cassiterite?

The chemical formula of Cassiterite is SnO2.

What crystal system does Cassiterite belong to?

Cassiterite crystallises in the Tetragonal crystal system.

Where is Cassiterite found?

Notable localities for Cassiterite include Yaogangxian Mine, Xianghualing Mine, Gejiu Mine, Cornwall, Xuebaoding, Pingwu.

Is Cassiterite rare?

As a collector mineral, Cassiterite is generally considered uncommon.

Related minerals

Available Cassiterite specimens

23 specimens
Black cassiterite crystal on pale muscovite mica from Xuebaoding, Sichuan, China
Xuebaoding, Pingwu · China

Black Cassiterite with Mica — Xuebaoding, Sichuan · 7 cm

$153.99
Black cassiterite crystals on pearly muscovite mica from Xuebaoding, Sichuan, China
Xuebaoding, Pingwu · China

Black Cassiterite with Mica — Xuebaoding, Sichuan · 6.7 cm

$193.99
Plate of gemmy brown cassiterite on white quartz from Yunnan, China
Yunnan Province · China

Gemmy Brown Transparent Cassiterite with Quartz — Yunnan

$148.99
Glossy black cassiterite crystals on white quartz from Yunnan, China
Yunnan Province · China

Glossy Black Cassiterite with Quartz — Yunnan, China

$65.99
Gemmy brown cassiterite crystal on white quartz from Yunnan, China
Yunnan Province · China

Transparent Cassiterite with Quartz — Yunnan, China

$84.99
Glossy black cassiterite crystals with honey citrine on white matrix from Yunnan, China
Yunnan Province · China

Cassiterite with Citrine — Yunnan, China

$116.99
Glossy brown cassiterite crystals below pale quartz points from Yunnan, China
Yunnan Province · China

Glossy Brown Cassiterite with Quartz — Yunnan, China

$187.99
Bladed black cassiterite crystal from Xuebaoding, Sichuan, China
Xuebaoding, Pingwu · China

Bladed Black Cassiterite — Xuebaoding, Sichuan, China

$25.99
Sale
Row of mirror-black cassiterite crystals on muscovite from Xuebaoding, Sichuan, China
Xuebaoding, Pingwu · China

Cassiterite with Mica — Xuebaoding, Sichuan, China · 6.8 cm

$150.00 $167.00
Sale
Black cassiterite and pale aquamarine prism on muscovite from Xuebaoding, Sichuan, China
Xuebaoding, Pingwu · China

Cassiterite with Aquamarine — Xuebaoding, Sichuan, China

$334.00 $371.00
Sale
Large black cassiterite with albite, calcite and mica from Xuebaoding, Sichuan, China, held in gloved hand
Xuebaoding, Pingwu · China

Cassiterite with Albite — Xuebaoding, Sichuan, China

$162.00 $180.00
Sale
Black cassiterite plate with yellow aquamarine from Xuebaoding, Sichuan, China, held in gloved hand
Xuebaoding, Pingwu · China

Black Cassiterite with Aquamarine — Xuebaoding · 7.2 cm

$816.00 $907.00
Cassiterite from Xuebaoding, China: black crystals beside a silvery mica patch.
Xuebaoding, Pingwu · China

Black Cassiterite with Silvery Mica Cluster | Xuebaoding, China

$85.00
Cassiterite Aquamarine Mica Specimen Xuebaoding Sichuan China - Classic Tin Crystal Aqua Beryl Combination - SKU H1028
Xuebaoding, Pingwu · China

Cassiterite & Aquamarine on Muscovite, Xuebaoding, Sichuan

$971.82
Cassiterite on muscovite mica from Xuebaoding, Sichuan
Xuebaoding, Pingwu · China

Cassiterite on Muscovite Mica, Xuebaoding, Sichuan, China

$230.00
Cassiterite and quartz cluster from Yaogangxian Mine, China
Yaogangxian Mine · China

Cassiterite and Quartz Cluster, Yaogangxian Mine, China

$290.00
Cassiterite in association with clear quartz from Yaogangxian Mine, Hunan
Yaogangxian Mine · China

Cassiterite with Quartz – Yaogangxian Mine, Hunan, China

$800.00
Cassiterite and quartz cluster with purple fluorite, Yaogangxian Mine, Hunan
Yaogangxian Mine · China

Cassiterite on Purple Fluorite with Quartz, Yaogangxian

$145.00
Cassiterite crystal with aquamarine and mica from Xuebaoding Mountain, Sichuan
Xuebaoding, Pingwu · China

Black Cassiterite with Muscovite and Aquamarine, Xuebaoding

$285.00
Sale
Black columnar cassiterite crystal with striations, Yaogangxian Mine, Hunan
Yaogangxian Mine · China

Striated Cassiterite Group on Quartz, Yaogangxian Mine, Hunan

$252.00 $280.00
Sale
Black cassiterite crystal with octahedral form, Xuebaoding Mountain, Sichuan
Xuebaoding, Pingwu · China

Cassiterite Crystal Cluster, Xuebaoding Mt., Sichuan

$121.50 $135.00
Sale
Blue Cassiterite Cluster Xuebaoding Pingwu
Xuebaoding, Pingwu · China

Cassiterite with Aquamarine, Muscovite & Quartz – Xuebaoding, Sichuan

$629.10 $699.00
Sale
Black Octahedral Cassiterite from Xuebaoding, Pingwu, Sichuan
Xuebaoding, Pingwu · China

Cassiterite Crystal Specimen, Xuebaoding Mountain, China

$2,070.00 $2,300.00

Recently sold Cassiterite specimens

4 examples — for reference

External references

Cassiterite on Mindat.org · Wikidata.